Volume of a deflated football

Which statement justifies that phosphine (ph3) is a polar molecule?

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

24. a sports ball is inflated to an internal pressure of 1.85 atm at room temperature (25 °c). if the ball is then played with outside where the temperature is 7.5 °c, what will be the new pressure of the ball? assume the ball does not change in volume nor does any air leak from the ball a) 0.555 atm b) 1.74 atm c) 1.85 atm d) 1.97 atm