Please help, need to get theis right

Match the mixture with the substance// i really need on this guys (it’s a pic btw)

How many moles of lead are in 1.50 x 10^12 atoms of lead? could you explain the answer as well and not just give it to me i am refreshing for finals and i need to know how to do it

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. in the first step, calcium carbide and water react to form acetylene and calcium hydroxide: cac2 (s) + 2h2o (g) → c2h2 (g) + caoh2 (s) =δh−414.kj in the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6c2h2 (g) + 3co2 (g) + 4h2o (g) → 5ch2chco2h (g) =δh132.kj calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. round your answer to the nearest kj .