Draw the d-orbital splitting for an octahedral and a tetrahedral complex.

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Explanation:

In an octahedral crystal field, the metal is at the centre of an octahedron with ligands at the six corners of the octahedron. Approach of the ligand splits the orbitals into higher energy eg and lower energy t2g orbitals. The eg orbitals are 0.6∆o above the bari centre while the t2g orbitals are -0.4∆o below the bari centre.

In a tetrahedral crystal field, the tetrahedral crystal field splitting ∆t= 4/9∆o. In the tetrahedral crystal field, the t2 orbitals are at a higher energy and are +0.4∆t above the bari centre while the e orbitals are at a lower energy and are -0.6∆t below the bari center.

most historians agree that gabriel mouton, the vicar of st. paul’s church in lyons, france, is the “founding father” of the metric system. he proposed a decimal system of measurement in 1670. mouton based it on the length of one minute of arc of a great circle of the earth (now called a nautical mile, 1852 meters). he also proposed the swing-length of a pendulum with a frequency of one beat per second as the unit of length (about 25 cm). a pendulum beating with this length would have been fairly easy to produce, thus facilitating the widespread distribution of uniform standards. over the years, his work was revised, improved, and extended by a number of french scientists.

the political sponsor of weights and measures reform in the french revolutionary national assembly was the bishop of autun, better known as talleyrand. under his auspices, the french academy appointed several committees to carry out the work of developing a usable system of weights and measures for france. one of the committees recommended a decimalized measurement system based upon a length equal to one ten-millionth of the length of a quadrant of the earth’s meridian (i.e., one ten-millionth of the distance between the equator and the north pole).

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