: Starting with 0.3500 mol CO(g) and 0.05500 mol COCl2(g) in a 3.050-L flask at 668 K, how many moles of Cl2(g) will be present at equilibrium

The number of moles of Cl₂ present at equilibrium is 3.94x10⁻⁴ moles.

Explanation:

The reaction is:

CO(g) + Cl₂(g) ⇄ COCl₂(g)  

The equilibrium constant of the above reaction is:

K = 1.2x10³

To find the moles of Cl₂ present at equilibrium, let's evaluate the reverse reaction:

COCl₂(g) ⇄ CO(g) + Cl₂(g)  

The equilibrium constant for the reverse reaction is:

Now, we need to calculate the concentration of CO and COCl₂:

Now, from the reaction we have:

COCl₂(g) ⇄ CO(g) + Cl₂(g)  

0.018 - x       0.115+x   x    

The concentration of Cl₂ is:

By solving the above equation for x we have:

x = 1.29x10⁻⁴ M = [Cl₂]

Finally, the number of moles of Cl₂ present at equilibrium is:

Therefore, the number of moles of Cl₂ present at equilibrium is 3.94x10⁻⁴ moles.

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