Tubes through which water flows as it is brought from 0.8 MPa, 150C to 240C at essentially constant pressure in the boiler of a power plant. The total mass flow rate of the water is 100 kg/s. Combustion gases passing over the tubes cool from 1067 to 547C at essentially constant pressure. The combustion gases can be modeled as air as an ideal gas. There is no significant heat transfer from the boiler to its surroundings. Surrounding (dead state) temperature and pressure are given as 25C and 1 atm, respectively. Determine i) the exergetic efficiency of the boiler ii) rate of exergy destruction as kW iii) mass flow rate of the combustion gases as kg/s

Determine the  wavelength of light emitted when an electron  in an li2+ ion  makes a transition from an orbital with n  =  6 to an orbital with n  = 5.

Answerthis solution will not form a precipitateexplanationsolubility equilbrium:         pbf₂(s)  ⇄ pb²⁺(aq) + 2 f⁻(aq)the solubility product expression is    (we exclude solids from the equilibrium expression).now suppose we have the trial ion product q, which we can define as    then, we can interpret  q as the product of the concentration of the ions that we have and ksp as the product of the ion concentrations that are needed to form a saturated solution.if q > ksp, then that implies that there will be a surplus of ions that exceed the amount that is required to form a saturated solution. a precipitate will then form (the precipitate continually  forms until the surplus ions are removed and q is decreased to ksp's value).if q = ksp, the saturated solution that forms is barely saturated and the precipitate will be minimal.if q < ksp, then the ion concentration will not be enough to form a saturated solution (so no precipitate).using our information, we calculate the trial ion product:     since q = 2.7  × 10⁻⁸ < ksp =  4  ×  10⁻⁸, a precipitate will not form.

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