How does the sun rise and set on the spring and fall equinox

Asample of silver (with work function ? = 4.52 ev) is exposed to an ultraviolet light source (? = 200 nm), which results in the ejection of photoelectrons. what changes will be observed if: silver is replaced with copper (? = 5.10 ev) more photoelectrons ejected no photoelectrons are emitted fewer photoelectrons ejected more energetic photoelectrons (on average) less energetic photoelectrons (on average)

If i initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 k, and then i raise the pressure to 14 atm and increase the temperature to 300 k, what is the new volume of the gas?

May someone me with these science questions