1. Which of the following choices demonstrates the law of constant composition? (Slides 2 ‒ 3: Laws on Matter) (a) Nitrogen and oxygen are both found in nature as diatomic molecules. (b) When 20.0 g of nitrogen and 32.0 g of oxygen are combined and allowed to react in two separate experiments, both times the product isolated from reaction contains 14.0 g of nitrogen and 32.0 g of oxygen. (c) Nitrogen and oxygen gases are mixed to produce a sample consisting of 20.0 g of nitrogen and 32.0 g of oxygen. (d) When 14.0 g of nitrogen and 32.0 g of oxygen are mixed and react, there is no measurable change in mass during the reaction. (e) Nitrogen and oxygen are gases found in air, nitrogen is approximately 79% of air and oxygen is approximately 21%.

(b) When 20.0 g of nitrogen and 32.0 g of oxygen are combined and allowed to react in two separate experiments, both times the product isolated from reaction contains 14.0 g of nitrogen and 32.0 g of oxygen.

Explanation:

The law of definite proportion states that a gen chemical compound always contains its constituent elements in a fixed ratio by mass, independent on the method of preparation.

The molar mass of Nitrogen and Oxygen would always remain the same, allowing for exact reactant masses (or mole ratio) irrespective of the given amount of sample.

1. 1 mole of anything contains 6.022x10^23 pieces  

d  

2. a  

3. c, number  

5. 1.24x10^24atoms / 6.022x10^23atoms/mole = 2moles h2 atoms  

6. fe2br3 mass = 2moles x mass fe + 3 moles x mass br  

molar mass = grams / number of moles = g/mole  

to find moles = g / molar mass  

to find mass = g = molar mass / moles