When limestone (solid ) is heated, it decomposes into lime (solid ) and carbon dioxide gas. This is an extremely useful industrial process of great antiquity, because powdered lime mixed with water is the basis for mortar and concrete — the lime absorbs from the air and turns back into hard, durable limestone. Suppose a limekiln of volume is pressurized with carbon dioxide gas to , and heated to . When the amount of has stopped changing, it is found that of have appeared. Calculate the pressure equilibrium constant this experiment suggests for the equilibrium between and at . Round your answer to significant digits. Note for advanced students: it's possible there was some error in this experiment, and the value it suggests for does not match the accepted value.

Problem #3 (ch. 1, problem 15)the ideal gas law provides one way to estimate the pressure exerted by a gas on a container. the law isí‘ťí‘ť=푛푛푛푛푛푛푉푉mo re accurate estimates can be made with the van der waals equationí‘ťí‘ť=í‘›í‘›í‘›í‘›í‘›í‘›í‘ ‰í‘‰â’푛푛푟푟â’푞푞푛푛2í‘ ‰í‘‰2where the term nb is a correction for the volume of the molecules and the term an2/v2is a correction for molecular attractions. the values of a and b depend on the type of gas. the gas constant is r, the absolutetemperature is t, the gas volume is v, and the number of moles of gas molecules is indicated by n. if n = 1 mol of an ideal gas were confined to a volume of v = 22.41 l at a temperature of 0â°c (273.2k), it would exert a pressure of 1 atm. in these units, r = 0.0826.for chlorine gas (cl2), a = 6.49 and b = 0.0562. compare the pressure estimates given by the ideal gas law and the van der waals equation for 1 mol of cl2 in 22.41 l at 273.2 k. what is the main cause of the difference in the two pressure estimates, the molecular volume or the molecular attractions?

The atomic radius of sodium is 186 pm and of chlorine is 100 pm. the ionic radius for na+ is 102 pm and for cl– is 181 pm. in going from na to cl in period 3, why does the atomic radius decrease while the ionic radius increases? a. the inner electrons in the sodium cation shield its valence electrons more effectively than the inner electrons in the chloride anion do. b. the inner electrons shield the valence electrons more effectively in the chlorine atom than in the chloride anion. c. the outermost electrons in chloride experience a smaller effective nuclear charge than those in the sodium cation do. d. the outermost electrons in chloride experience a larger effective nuclear charge than those in the sodium cation do. e. monatomic ions are bigger than the atoms from which they are formed.

If you have 5.25 grams of methane (ch4), how many grams of co2 will you produce ?