23.495 g sample of aqueous waste leaving a fertilizer manufacturer contains ammonia. The sample is diluted with 72.311 g of water. A 12.949 g aliquot of this solution is then titrated with 0.1080 M HCl . It required 32.27 mL of the HCl solution to reach the methyl red endpoint. Calculate the weight percent NH3 in the aqueous waste.

1.86% NH₃

Explanation:

The reaction that takes place is:

We calculate the moles of HCl that reacted, using the volume used and the concentration:

The moles of HCl are equal to the moles of NH₃, so now we calculate the mass of NH₃ that was titrated, using its molecular weight:

The weight percent NH₃ in the aliquot (and thus in the diluted sample) is:

Now we calculate the total mass of NH₃ in the diluted sample:

Diluted sample total mass = Aqueous waste Mass + Water mass = 23.495 + 72.311 = 95.806 g

Finally we calculate the weight percent NH₃ in the original sample of aqueous waste:

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