Find the temperature at which Kp = 4.00 for the reaction N2O4(g) ⇋ 2NO2(g). [Given: at 25°C, for NO2(g), LaTeX: \triangle △H°f = 33.85 kJ/mol, S° =240.46 J/mol·K; for N2O4(g), LaTeX: \triangle △H°f = 9.66 kJ/mol, S° =304.3 J/mol·K; assume that LaTeX: \triangle △H° and LaTeX: \triangle △S° are independent of temperature.]

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Vander waals forces are inter molecular bonds that exist within molecules of the same substance. a water molecule is made up of oxygen and hydrogen atoms which share electrons between each other. the vander waals forces are forces that exist between multitude of different  molecules of water. dipole dipole forces is the type of vander waals force that exist in water. the oxygen atom which is more electronegative pulls the shared electron closer to itself thus generating a partial negative charge while the hydrogen acquire a partial positive charge. these two different charges causes attraction to occur in water molecules.