In a constant‑pressure calorimeter, 60.0 mL of 0.300 M Ba ( OH ) 2 was added to 60.0 mL of 0.600 M HCl . The reaction caused the temperature of the solution to rise from 22.74 ∘ C to 26.83 ∘ C. If the solution has the same density and specific heat as water, what is heat absorbed by the solution?

Q sln = 75.165 J

Explanation:

a constant pressure calorimeter:

∴ m sln = m Ba(OH)2 + m HCl

∴ molar mass Ba(OH)2 = 171.34 g/mol

∴ mol Ba(OH)2 = (0.06 L)(0.3 mol/L) = 0.018 mol

⇒ mass Ba(OH)2 = (0.018 mol)(171.34 g/mol) = 3.084 g

∴ molar mass HCl = 36.46 g/mol

∴ mol HCl = (0.06 L)(0.60 mol/L) = 0.036 mol

⇒ mass HCl = (0.036 mol)(36.46 g/mol) = 1.313 g

⇒ m sln = 3.084 g + 1.313 g = 4.3966 g

specific heat (C):

∴ C sln = C H2O = 4.18 J/g°C

∴ ΔT = 26.83°C - 22.74°C = 4.09°C

heat absorbed (Q):

⇒ Q sln = (4.3966 g)(4.18 J/g°C)(4.09°C)

⇒ Q sln = 75.165 J

the dissociation of nickel hydroxide is follows:

the concentration of hydroxide ion is

the equilibrium constant value of nickel hydroxide is = 6.1 * 10^-^1^6 and thus equilibrium equation can be written as:

thus, concentration of ni is 0.23 * 10^-^4 mol /l