What volume of methanol should be used to make 1.25 l of a 21.0 by volume solution

The density of the solid phase of a substance is 0.90 g/cm3 and the density of the liquid phase is 1.0 g/cm3. a large increase in pressure will a. lower the freezing point b. raise the freezing point c. lower the boiling point d. raise the triple point e. lower the triple point