For the reaction:

2ClO2(aq) + 2OH-(aq) > ClO3-(aq) + ClO2-(aq) + H2O(l),

the following data were obtained

Experiment [ClO2](M) [OH−](M) Rate (M/s)
1 0.060 0.030 0.0248
2 0.020 0.030 0.00276
3 0.020 0.090 0.00828

What is the magnitude of the rate constant for the reaction in units M-2 s-1

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

un recipient conține 6,4 moli de gaz. gazul hidrogen reprezintă 25% din totalul kilometrilor din container. în cazul în care presiunea totală este de 1.24 atm ceea ce este

on passing the small ampere of electric current through the tube made of ar and hg of cfl generates uv rays which excites the fluorescent and thus emits the high radiation by consumption of just 5- 12 w in comparison to incandescent light which requires more power such as around 40 - 55 w to lighten.

moreover the life span of fluorescent or cfl is around 8000 h whereas the life span of incandescent is around 1200 h

hence, the building installed with incandescent lights bears more electricity bill.

the answer is symmetrical : )