An electrode has a potential of 1.201 V with respect to a saturated silver-silver chloride electrode. What would the electrodes potential be relative to a saturated calomel electrode (S. C.E.)? E = 0.197 V for the saturated silver-silver chloride electrode and E = 0.241 V for the S. C.E.

The potential wrt. calomel is 1.254 V

Explanation:

Given:

Potential wrt. silver chloride V

Potential wrt. saturated silver chloride V

Potential wrt. SCE V

Now potential wrt. hydrogen is given by,

    V

And we find for potential wrt. calomel,

    potential wrt. hydrogen + potential wrt. SEC

    V

Therefore, the potential wrt. calomel is 1.254 V

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