Suppose a student started with 142.0 mg of trans-cinnamic acid, 412 mg of pyridinium tribromide, and 2.30 mL of glacial acetic acid. After the reaction and workup, the student ended up with 0.2223 g of brominated product. Calculate the student\'s theoretical and percent yields.

Theoretical Yield = 0.2952 g

               Percentage Yield = 75.3%

Explanation:

Calculation of limiting reactant:

n-trans-cinnamic acid moles = (142mg/1000) / 148.16 = 9.584*10⁻⁴ mol

pyridium tribromide moles = (412mg/1000) / 319.82= 1.288*10⁻³ mol

The molar ratio according to the equation mentioned is equals to 1:1

The brominated product moles is also = 9.584*10⁻⁴ mol

Theoretical yield = (9.584*10⁻⁴ mol) * (Mr of brominated product)

                             =  (9.584*10⁻⁴ mol) * (307.97) = 0.2952 g

Percentage Yield is : Actual Yield / Theoretical Yield = 0.2223/0.2952

                                                                                           = 75.3%

d is

answer: the enthalpy of the overall chemical reaction is +87.88 kj or +88 kj.

according to hess's law, the overall enthalpy of a reaction is the difference between the sum of enthalpy values of all the products and the sum of enthalpy values of all the reactants.

δh(reaction) = ∑nδh(products) - ∑nδh(reactants)

δh(reaction) = [δh +δh] - [δh]

δh(reaction) = [1(-287.02) + 1(0) ] - [1(-374.9)] kj = +87.88 kj

here, δh (pcl3) = -287.02 kj, δh(cl2) = 0, δh(pcl5) = -374.9 kj

therefore, enthalpy of the overall reaction is +87.88 kj or +88 kj.