A sucrose solution is prepared to a final concentration of 0.250 M . Convert this value into terms of g/L, molality, and mass %. (Use the following values: molecular weight MWsucrose = 342.296 g/mol ; density rhosol′n = 1.02 g/mL ; and mass of water, mwat = 934.4 g ). Note that the mass of solute is included in the density of the solution.

A. 85.6 g

= 0.0856 kg.

B. 0.00027 mol/g

= 0.27 mol/kg.

C. 8.39 %

Explanation:

Given:

Molar concentration = 0.25 M

Molar weight of sucrose = 342.296 g/mol

Density of solution = 1.02 g/mL

Mass of water = 934.4 g.

Density in g/l = 1.020 g/ml * 1000ml/1 l

= 1020 g/l

Mass of solution in 1 l of solution = 1020 g

Mass of solution = mass of solvent + mass of solute

Mass of sucrose = 1020 - 934.4

= 85.6 g of sucrose in 1 l of solution.

A.

Density of sucrose = mass/volume

= molar mass/molar concentration

= 342.296 * 0.25

= 85.6 g/l

Number of moles = mass/molar mass

= 85.6/342.296

= 0.25 mol

B.

Molality = number of moles of solute/mass of solvent

= 0.25/934.4

= 0.00027 mol/g

C.

% mass of sucrose = mass of sucrose/total mass of solution * 100

= 85.6/1020 * 100

= 8.39 %

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the   per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:                   1 - α               α               α           = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

=  

or,

or,   = (at v = 1l)

the reaction:                     so₂cl₂ (g) = so₂ (g) + cl₂ (g)         total

the moles at equilibrium:   1 - α                 α               α           = 1+α

concentrations:               (1 - α)/0.5           α/0.5         α/0.5       = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

or,  

=  

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

the volume increases