A white crystalline compound melts at 111°–112°C and the melting-point capillary is set aside to cool. Repeating the melting- point analysis with the same capillary reveals a much higher melting point of 140°C. Yet repeated recrystallization of the original sample yields sharp melting points no higher than 114°C. Explain the behavior of the sample that was cooled and then remelted.

Why do sodium and neon have vastly different chemical and physical properties despite having similar atomic masses?

Straightforward questions answered in the powerpoint slidesreaction: heating the starting materials under refluxwhat does it mean to heat under reflux? why do we choose water as the reflux solvent? what are boiling chips used for? why do we put a condenser on top of the reaction? why do we add heat and let the reaction stir for 30 minutes? why do we add sulfuric acid to the reaction after it cools as opposed to when it’s still hot? separation: filtration of precipitatewhy don’t we do an aqueous and organic extraction in the separatory funnel? why do you rinse the salicylic acid on the filter with ice cold water? purification: recrystallization of salicylic acid (no hot filtration needed)what is the difference in the amount of room temperature water vs. boiling water needed to dissolve the salicylic acid (assume a 1.2 gram yield of salicylic acid)? remember, in the lab if you need x ml of boiling water to dissolve a solid, then you should add a little more (definitely no more than 1.5 times the theoretical amount) to ensure it doesn’t recrystallize prematurely. analysis: melting point of salicylic acidwhat can you conclude if the melting point of the salicylic acid you just synthesized is 152-155oc and the 1: 1 mix of your product and “synthetic” salicylic acid is 151-154oc?

Lab reagent, hypothesis test. a reference solution used as a lab reagent is purported to have a concentration of 5 mg/dl. six samples are taken from this solution and the following concentrations are recorded: (5.32, 4.88, 5.10, 4.73, 5.15, 4.75) mg/dl. these six measurements are assumed to be an srs of all possible measurements from solution. they are also assumed to have a standard deviation of 0.2, a normal distributin, and a mean concentration equal to the true concentration of the solution. carry out a significance test to determine whether these six measurements provide reliable evidence that the true concentration of the solution is actually not 5 mg/dl.