3.
a gas has a volume of 225 l at 175 k and 150 kpa. what will be its volume at a temperature
of 112 k and pressure remains constant?
4
.
a gas is heated to 180 k at a constant pressure of 1 atm. if the container expands to hold a
volume of 44.8 l, what was the volume of the gas, at a temperature of 90 k?
a 200 l sample of gas is collected at 50 kpa and a temperature of 271 k. what volume
would this gas occupy at 100 kpa and a temperautre of 14 k?
6.
find the new volumes if the values given below change to stp (273 k and 101.3
(a) 24.6 l at 25°c and 10 atm

3. V = 0.2673 L

4. V = 2.4314 L

5. V = 0.262 L

6. V = 2.224 L

Explanation:

3. assuming ideal gas:

∴ R = 0.082 atm.L/K.mol

∴ V1 = 225 L

∴ T1 = 175 K

∴ P1 = 150 KPa = 1.48038 atm

⇒ n = RT/PV

⇒ n = ((0.082 atm.L/K.mol)(175 K))/((1.48038 atm)(225 L))

⇒ n = 0.043 mol

∴ T2 = 112 K

∴ P2 = P1 = 150 KPa = 1.48038 atm

⇒ V2 = RT2n/P2

⇒ V2 = ((0.082 atm.L/K.mol)(112 K)(0.043 mol))/(1.48038 atm)

⇒ V2 = 0.2673 L

4. gas is heated at a constant pressure

∴ T1 = 180 K

∴ P = 1 atm

∴ V1 = 44.8 L

⇒ n = RT/PV

⇒ n = ((0.082 atm.L/K.mol)(180 K))/((1 atm)(44.8 L))

⇒ n = 0.3295 mol

∴ T2 = 90 K

⇒ V2 = RT2n/P

⇒ V2 = ((0.082 atm.L/K.mol)(90 K)(0.3295 mol))/(1 atm)

⇒ V2 = 2.4314 L

5.  V1 = 200 L

∴ P1 = 50 KPa = 0.4935 atm

∴ T1 = 271 K

⇒ n = RT/PV

⇒ n = ((0.082 atm.L/K.mol)(271 K))/((0.4935 atm)(200 L))

⇒ n = 0.2251 mol

∴ P2 = 100 Kpa = 0.9869 atm

∴ T2 = 14 K

⇒ V2 = RT2n/P2

⇒ V2 = ((0.082 atm.L/K.mol)(14 K)(0.2251 mol))/(0.9869 atm)

⇒ V2 = 0.262 L

6.a)  ∴ V1 = 24.6 L

∴ P1 = 10 atm

∴ T1 = 25°C = 298 K

⇒ n = RT/PV

⇒ n = ((0.082 atm.L/K.mol)(298 K))/((10 atm)(24.6 L))

⇒ n = 0.0993 mol

∴ T2 = 273 K

∴ P2 = 101.3 KPa = 0.9997 atm

⇒ V2 = RT2n/P2

⇒ V2 = ((0.082 atm.L/K.mol)(273 K)(0.0993 mol))/(0.9997 atm)

⇒ V2 = 2.224 L

he uptake of drugs from the intestine is often strongly influenced by diffusion. for example, consider a water-insoluble steroid for treating inflammation that is solubilized in aggregates of detergent molecules, called micelles. these micelles, aggregates of 80 soap molecules, have a molecular weight of 24,000, a diameter of 2.6 nm, and a charge of -27. the positively charge ions (counterions) in this system are na".