Chemistry, 11.01.2020 04:31 smariedegray

Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine.

the data refer to 298 k.

so2(g) + cl2(g) --> so2cl2(g)

substance: so2(g) + cl2(g) -> so2cl2(g)

delta h� f (kj/mol): �296.8 0�364.0

delta g� f (kj/mol): �300.1 0 �320.0

delta s�(j/kmol): 248.2 223.0 311.9

what is the value of g� for this reaction at 600 k?

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Answer from: acediego3119

The value of $\Delta G^o$ of the reaction is 28.38 kJ/mol

Explanation:

For the given chemical reaction:

$SO_2(g)+Cl_2(g)\rightarrow SO_2Cl_2(g)$

The equation used to calculate enthalpy change is of a reaction is:

$\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]$

The equation for the enthalpy change of the above reaction is:

$\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(SO_2Cl_2(g))})]-[(1\times \Delta H^o_f_{(SO_2(g))})+(1\times \Delta H^o_f_{(Cl_2(g))})]$

We are given:

$\Delta H^o_f_{(SO_2Cl_2(g))}=-364kJ/mol\\\Delta H^o_f_{(SO_2(g))}=-296.8kJ/mol\\\Delta H^o_f_{(Cl_2(g))}=0kJ/mol$

Putting values in above equation, we get:

$\Delta H^o_{rxn}=[(1\times (-364))]-[(1\times (-296.8))+(1\times 0)]=-67.2kJ/mol=-67200J/mol$

The equation used to calculate entropy change is of a reaction is:

$\Delta S^o_{rxn}=\sum [n\times \Delta S^o_f_{(product)}]-\sum [n\times \Delta S^o_f_{(reactant)}]$

The equation for the entropy change of the above reaction is:

$\Delta S^o_{rxn}=[(1\times \Delta S^o_{(SO_2Cl_2(g))})]-[(1\times \Delta S^o_{(SO_2(g))})+(1\times \Delta S^o_{(Cl_2(g))})]$

We are given:

$\Delta S^o_{(SO_2Cl_2(g))}=311.9J/Kmol\\\Delta S^o_{(SO_2(g))}=248.2J/Kmol\\\Delta S^o_{(Cl_2(g))}=223.0J/Kmol$

Putting values in above equation, we get:

$\Delta S^o_{rxn}=[(1\times 311.9)]-[(1\times 248.2)+(1\times 223.0)]=-159.3J/Kmol$

To calculate the standard Gibbs's free energy of the reaction, we use the equation:

$\Delta G^o_{rxn}=\Delta H^o_{rxn}-T\Delta S^o_{rxn}$

where,

$\Delta H^o_{rxn}$ = standard enthalpy change of the reaction =-67200 J/mol

$\Delta S^o_{rxn}$ = standard entropy change of the reaction =-159.3 J/Kmol

Temperature of the reaction = 600 K

Putting values in above equation, we get:

$\Delta G^o_{rxn}=-67200-(600\times (-159.3))\\\\\Delta G^o_{rxn}=28380J/mol=28.38kJ/mol$

Hence, the value of $\Delta G^o$ of the reaction is 28.38 kJ/mol

Answer from: Quest

explanation:

metals have excess of electrons whereas non-metals have deficiency of electrons. thus, in order to gain stability metals easily donate their electrons to the non-metals.

for example, electronic configuration of sodium is $1s^{2}2s^{2}2p^{6}3s^{1}$ and electronic configuration of phosphorous is $1s^{2}2s^{2}2p^{6}3s^{2}3p^{3}$ .

when a phosphorous atom and sodium atom combine together then sodium will donate is extra one electron to the phosphorous atom. as a result there will be formation of ionic bond between sodium and phosphorous.

the reaction will be as follows.

$3na + p \rightarrow na_{3}p$

there, are three sodium sodium atoms and each of them will donate its one extra electron to phosphorous atom. thus, the sub-shell of phosphorous gets completely filled.

thus, we can conclude that electrons are transferred from atoms of sodium to atoms of phosphorous. this transfer makes the sodium atoms donate one electron and the phosphorous atoms to gain one electron. as a result, the sodium and phosphorus atoms strongly attract each other.