Since acids have 1 more proton (h+ - ions) than base, and the acid gives it away, doesn't that mean that they switch roles? acid becomes base, and base becomes

for clarifying .. : )

In an acid-base equilibrium, acid becomes a conjugate base and base becomes a conjugate acid.

Explanation:

Let's remember the Bronsted-Lowry theory to answer this specific question. According to the theory, acid is a proton donor, while a base is a proton acceptor.

Consider an acid in a form HA (aq) and base in a form of B (aq). Since acid is a proton donor, it will donate its hydrogen ion to the base, B. The resultant products would be (aq) and (aq).

Remember that an acid-base reaction is an equilibrium reaction. This means we may also look at this proton transfer reaction from the product side towards the reactants. Summarizing what has been said, we may write the equilibrium as:

⇄

Now acid, HA, donates a proton to become a conjugate base. The conjugate base, if we look from the reverse equation side, is actually a base, since it can accept a proton to become HA. Similarly, B accepts a proton to become a conjugate acid. Looking from the reverse reaction, it can now donate a proton, so in reality we can consider it a base.

To summarize, your logic is correct.

the answer is   c.) 1575 j.

explanation:

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol