Jeff and jill go canoeing. while reaching to feed a duck, the boat flips. jeff and jill blow up their inflatable life preservers and then put them on. as they wait for the rescue squad, they calculate how much nitrogen is in each life preserver. they estimate that the volume is 14 l, pressurized to 1.1 atm at 25°c. the air used for inflation is 80% nitrogen by volume and 20% oxygen by volume. give the amount of nitrogen gas. answer in units of grams.

Lem 2 the data below are for the system ethyl propyl ether (1)-chloroform (2) at 0.5 bar. use the data to answer the following questions (all questions refer to p d 0: 5 bar). a) what are the boiling points of the pure components at 0.5 bar? b) a mixture with the overall composition z1 d 0: 1 is brought to 47.6ä±c, 0.5 bar. what is the phase? c) 100 mole of a mixture with z1 d 0: 1 (state a) is mixed with 22 mole of pure ethyl propyl ether vapor (state b). the mixing takes place at 47.6 ä±c, 0.5. bar. what is the phase of the resulting mixture (state c)? if the state is a v/l mixture report the number of moles and mole fractions in each phase. d) plot the txy graph and show states a, b and c. the graph must be done by computer and should be properly annotated. ethyl propyl ether (1) - chloroform (2) at 0.5 bar t ( ä±c) x1 y1 t ( ä±c) x1 y1 42.9 0.000 0.000 49.0 0.470 0.455 43.0 0.020 0.010 49.1 0.520 0.520 43.9 0.065 0.029 48.9 0.567 0.592 45.4 0.156 0.089 48.3 0.652 0.720 46.4 0.215 0.142 47.6 0.745 0.815 47.6 0.296 0.223 46.7 0.822 0.872 48.3 0.362 0.302 45.7 0.907 0.937 48.7 0.410 0.375 44.6 1.000

Consider three unlabeled bottles, each contain small pieces of one of the following metals. - magnesium - sodium - silver the following reagents are used for identifying the metals. - pure water - a solution of 1.0 molar hcl - a solution of concentrated hno3 (a) which metal can be easily identified because it is much softer than the other two? describe a chemical test that distinguishes this metal from the other two, using only one of the reagents above. write a balanced chemical equation for the reaction that occurs. (b) one of the other two metals reacts readily with the hcl solution. identify the metal and write the balanced chemical equation for the reaction that occurs when this metal is added to the hcl solution. use the table of standard reduction potentials (attached) to account for the fact that this metal reacts with hcl while the other does not. (c) the one remaining metal reacts with the concentrated hno3 solution. write a balanced chemical equation for the reaction that occurs. (d) the solution obtained in (c) is diluted and a few drops of 1 m hcl is added. describe what would be observed. write a balanced chemical equation for the reaction that occurs.

If a solution contains 3 moles/liter of sodium chloride (nacl, made of sodium ions and chloride ions), what is the osmolarity of this solution