Carbon monoxide binds strongly to the fe2+ ion of the haem group of the protein myoglobin. estimate the vibrational frequency of co bound to myoglobin by using the data below and by making the following assumptions: the atom that binds to the haem group is immobilized, the protein is infinitely more massive than either the c or o atom, the c atom binds to the fe2+ ion, and binding of co to the protein does not alter the force constant of the image from custom entry toolbond. (c triple bond o)

the following data on the infrared absorption wavenumbers ( wavenumbers in cm- 1) of molecules are taken from spectra of diatomic molecules, g. herzberg, van nostrand ( 1950):

h35cl 2990

h81br 2650

hi 2310

co 2170

no 1904

part 1: the half-life of the element is 22 years.

part 2: it will take 132.02 year for the sample to decay from 308.0 g to 4.8125 g.

explanation:

part 1: there are two ways to determine the half life time.

first way: the half life time can be determined directly from its definition as it is the time required for the sample to decay to its half concentration.

from the data the initial concentration was 45.0 g and decayed to its half value (22.5 g) in 22.0 years.

second way: the radio active decay is considered first order reaction so we can use the laws of first order reactions.

k = (1/t) ln (a/a-x), where k is the rate constant of the reaction,

t is the time of the reaction

a is the initial concentration of the reactant

a-x is the remaining concentration at time (t)

a = 45.0 g the initial concentration at t = 0 year.

at t = 22 year, a-x = 22.5 g

then k = (1/22 year) ln (45.0 g/ 22.5 g) = 0.0315 year-1.

the half-life time (t1/2) = ln 2/ k = 0.693/ k =0.693/ 0.0315 = 22 years.

part 2:

using the same law k = (1/t) ln (a/a-x),

using the given data; a = 308.0 g and a-x = 4.8125 g and the calculated k from the part 1 (k = 0.0315 year-1)

t = (1/k) ln (a/a-x) = (1/0.0315) ln (308.0/ 4.8125) = 132.02 years

answer: a tank of height h is filled with water and sits on the ground. water squirts from a hole at a height y above the ground and has a range r. for two y values, 0 and h, r is zero. determine the value of y for which the range will be a maximum.

explanation: