Which orbitals form a pi bond?

If anyone would be able to me out with these three questions it would be these are from the chem 2202 course.

How do cfcs cause ozone depletion? how do cfcs cause ozone depletion? ultraviolet radiation breaks down cfcs, molecules containing chlorine. chlorine then breaks one oxygen atom away from ozone, leaving behind a paired oxygen molecule. ultraviolet radiation breaks down cfcs, molecules containing chlorine. chlorine then breaks two oxygen atoms away from ozone, leaving behind a paired oxygen molecule. ultraviolet radiation creates cfcs, molecules containing chlorine. chlorine then breaks two oxygen atoms away from ozone, leaving behind a paired oxygen molecule. ultraviolet radiation creates cfcs, molecules containing chlorine. chlorine then breaks one oxygen atom away from ozone, leaving behind a paired oxygen molecule.

What would be the original temperature of a gas that has a volume of 2.0 l and a pressure of 2.0 atm and an unknown temperature that the volume increased to 3.5 l in its pressure decreased to 1.0 atm if the final temperature is measured to be 11°c