Arginine: a) draw the complete structure of the amino acid arginine in the form present at neutral ph. b) the pka of the carboxyl group is 2.1, the amino group is 9.6, and the r-group is 12.5. draw the form that would predominate at ph 9.8. c) on your structure in part b, carefully circle the atoms that can participate in hydrogen bonds when part of a peptide. d) calculate the net charge of free arginine at ph 9.8. show all of your work.

Answer asap need by wednesday morning explain how a buffer works, using an ethanoic acid/sodium ethanoate system including how the system resists changes in ph upon addition of a small amount of base and upon addition of a small amount of acid respectively. include the following calculations in your i. calculate the ph of a solution made by mixing 25cm3 0.1m ch3cooh and 40cm3 0.1m ch3coo-na+. [ka = 1.74 x 10-5 m] ii. calculate the ph following the addition of a 10cm3 portion of 0.08 m naoh to 500cm3 of this buffer solution. iii. calculate the ph following the addition of a 10cm3 portion of 0.08 m hcl to 200cm3 of the original buffer solution.