Hey i just need some on the two bottom questions. this is for ap chem and it’s about equilibrium constant

Explain in detail of the four major scientific developments that spurred the formulation of the plate tectonics theory

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.

What effect would average population growth have on land usage? a. urban use of land would rise to more than 30 percent of available land. b. industrial use of land would rise to more than 30 percent of available land. c. the percentage of available land used as cropland would stay the same. d. cropland would fall to about 10 percent of available land.