Ammonia reacts with oxygen to produce nitrogen and water?

- 1276.2 kJ.

Explanation:

ΔHrxn = ∑(n ΔHproducts) - ∑(n ΔHreactants)

∴ ΔHrxn = [(6 x ΔHf H₂O) + (2 x ΔHf N₂)] - [(4 x ΔHf NH₃) + (3 x ΔHf O₂)],

∴ ΔHrxn = [(6 x - 241.8 kJ/mol) + (2 x 0)] - [(4 x -45.9 kJ/mol) + (3 x 0)] = -1450.8 kJ/mol + 183.6 kJ/mol = - 1276.2 kJ.

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole