Can someone me here? find three examples from history of scientific ideas or theories that were changed, replaced, or rewritten in the face of newer evidence it would mean a lot !

In vapor-liquid equilibrium in a binary mixture, both components are generally present in both phases. how many degrees of freedom are there for such a system? the reaction between nitrogen and hydrogen to form ammonia occurs in the gas phase. how many degrees of freedom are there for this system? steam and coal react at high temperatures to form hydrogen, carbon monoxide, carbon dioxide, and methane. the following reactions have been suggested as being involved in the chemical transformation: