Chemistry, 27.06.2019 19:30 ccarwile01

Determine the rate law, including the values of the orders and rate law constant, for the following reaction using the experimental data provided. (4 points) a + b yieldsproducts trial [a] [b] rate 1 0.10 m 0.20 m 1.2 × 10-2 m/min 2 0.10 m 0.40 m 4.8 × 10-2 m/min 3 0.20 m 0.40 m 9.6 × 10-2 m/min

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Rate law= k[A]^1[B]^2 , order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is $3L^2mol^{-2}s^{-1}$

Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.

Rate=k[A]^x[B]^y

k= rate constant

x = order with respect to A

y = order with respect to A

n = x+y = Total order

a) From trial 1: $1.2\times 10^{-2}=k[0.10]^x[0.20]^y$ (1)

From trial 2: $4.8\times 10^{-2}=k[0.10]^x[0.40]^y$ (2)

Dividing 2 by 1 : $\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}$

4=2^y,2^2=2^y therefore y=2.

b) From trial 2: $4.8\times 10^{-2}=k[0.10]^x[0.40]^y$ (3)

From trial 3: $9.6\times 10^{-2}=k[0.20]^x[0.40]^y$ (4)

Dividing 4 by 3: $\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}$

2=2^x,2=2^1 , x=1

Thus rate law is Rate=k[A]^1[B]^2

Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.

c) For calculating k:

Using trial 1: $1.2\times 10^{-2}=k[0.10]^1[0.20]^2$

$k=3 L^2mol^{-2}s^{-1}$ .

Answer from: Quest

water molecules stay close to each other through cohesion, the collective action of hydrogen bonds between water molecules. cohesion plants draw water upwards from the root through the stem's transport tubes (xylem) to the leaf. this transport occurs even in large trees and against gravity. transpiration, evaporation of water from plant leaves, creates a tension on water molecules being pulled up from the stem and roots.

water also has high (the attraction of one substance to another) properties because of its polar nature. adhesion of water molecules to plant cell walls counteract gravity while water is transported from roots to leaves.

water exhibits a very high surface tension when compared to other liquids. surface tension is a property of a liquid that holds the surface together and allows it to resist an external force. by capillary action, the water forms concave menisci inside the pores. the high surface tension of water pulls the concavity outwards, generating enough force to lift water from the roots to the leaves of plants.

thus, cohesion, along with adhesion and surface tension creates a capillary action that keeps water molecules interacting and moving through the plants out to the leaf cells.

therefore, option d) is the correct answer.

explanation:

Answer from: Quest

The answer is c. 320 g